小松田雅晃博士

博士論文

脱芳香族的アリル化反応と開環型フッ素化反応

Dearomative Allylation of Unactivated Arenes and Ring-Breaking Fluorination of Azaarenes

研究業績

101. Dibenzofuran Synthesis: Decarbonylative Intramolecular C‐H Arylation of Aromatic Esters

Okita, T.; Komatsuda, M.; Saito, A. N,; Hisada, T.; Takahara, T. T.; Nakayama, K. P.; Isshiki, R.; Takise, R.; Muto, K.; Yamaguchi, J.
Asian J. Org. Chem. 2018, 7, 1358-1361.
DOI 10.1002/ajoc.201800207
Highlights Invitation to Contribute to a Special Issue: C–H Activation
Highlights the top 10% most downloaded papers between January 2018 and December 2019

103. Pd-Catalyzed Dearomative Allylation of Benzyl Phosphates

Komatsuda, M.; Muto, K.; Yamaguchi, J.
Org. Lett. 2018, 20, 4354–4357.
DOI 10.1021/acs.orglett.8b01807
Highlights Most Read Article

109. Pd-Catalyzed Dearomative Three-Component Reaction of Bromoarenes with Diazo Compounds and Allylborates

Komatsuda, M.; Kato, H.; Muto, K.; Yamaguchi, J.
ACS Catal. 2019, 9, 8991–8995.
DOI 10.1021/acscatal.9b03461
ChemRxiv, 2019,
DOI 10.26434/chemrxiv.8989130
Highlights Most Read Article (September, 2019)

114. Dearomative Allylation of Naphthyl Cyanohydrins by Palladium Catalysis: Catalyst-Enhanced Site Selectivity

Yanagimoto, A.; Komatsuda, M.; Muto, K.; Yamaguchi, J.
Org. Lett. 2020, 22, 3423–3427.
DOI 10.1021/acs.orglett.0c00897
ChemRxiv. 2020, preprint
DOI 10.26434/chemrxiv.11961987

115. Pd-Catalyzed C4-Dearomative Allylation of Benzyl Ammoniums with Allyltributylstannane

Kayashima, Y.; Komatsuda, M.; K.; Muto, K.; Yamaguchi, J.
Chem Lett. 2020, 49, 836–839.
DOI 10.1246/cl.200216
Highlights Selected as Editior’s Choice
Highlights Selected as an Inside cover
Highlights Most Read Article (July, 2020)
ChemRxiv. 2020, preprint
DOI 10.26434/chemrxiv.12015663

121.Catalytic Three-component C–C Bond Forming Dearomatization of Bromoarenes with Malonates and Diazo Compounds

Kato, H.; Musha, I.; Komatsuda, M.; Muto, K.; Yamaguchi, J.
Chem. Sci. 2020, 11, 8779 – 8784
DOI 10.1039/D0SC02881A
ChemRxiv. 2020, preprint
DOI 10.26434/chemrxiv.12234740

129. Ring-Opening Fluorination of Bicyclic Azaarenes

Komatsuda, M.; Suto, A.; Kondo Jr. H.; Takada, H.; Kato, K.; Saito, M.; Yamaguchi, J.
Chem. Sci. 2022, 13, 665–670.
DOI 10.1039/d1sc06273e
Highlights Selected as Cover picture
ChemRxiv. 2021, preprint
DOI 10.33774/chemrxiv-2021-gh325-v2

131. Pd-Catalyzed Asymmetric Dearomative Arylation of Indoles via a Desymmetrization Strategy

Nie, Y.-H.; Komatsuda, M.; Yang, P.; Zheng, C.; Yamaguchi, J.; You, S.-L. .
Org. Lett. 2022, 24, 1481–1485.
DOI 10.1021/acs.orglett.2c00129

133. Ring-Opening Fluorination of Isoxazoles

Komatsuda, M.; Ohki, H.; Kondo Jr., H.; Suto, A.; Yamaguchi, J.
Org. Lett. 2022, 24, 3270–3274
DOI 10.1021/acs.orglett.2c01149
ChemRxiv. 2022, preprint
DOI 10.26434/chemrxiv-2022-bj42g 

144. Ring-opening Fluorination of Carbo/Heterocycles and Aromatics: Construction of Complex and Diverse Fluorine-containing Molecules

Komatsuda, M.; Yamaguchi, J.
Chem. Rec. 2023, e20220028.
DOI 10.1002/tcr.202200281

コメント

脱芳香族的官能基化反応開発の初期メンバー。ベンジルアルコール類の脱芳香族的官能基化反応を３成分反応へと引き上げた。その後、脱芳香族的なフッ素化反応の開発に転身。有用なフッ素化反応にまとめ上げた。すべてにおいてよくできた大学院生。

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